Single Scan 2D NMR Spectroscopy on a 25 T Bitter Magnet.
نویسندگان
چکیده
2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multiscan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D "ultrafast" acquisition schemes, which correlate interactions along all spectral dimensions within a single scan.
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عنوان ژورنال:
- Chemical physics letters
دوره 442 4-6 شماره
صفحات -
تاریخ انتشار 2007